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| H (Match allé) | River Plate | - | Cruzeiro | 0:0 (0:0) | ||
| R (match retour) | Cruzeiro | - | River Plate | 2:4 (0:0, 0:0) tab | ||
| H (Match allé): 24.07.2019 00:15 | R (match retour): 31.07.2019 00:15 | vainqueur: River Plate | ||||
| H (Match allé) | Godoy Cruz | - | Palmeiras | 2:2 (2:1) | ||
| R (match retour) | Palmeiras | - | Godoy Cruz | 4:0 (0:0) | ||
| H (Match allé): 24.07.2019 02:30 | R (match retour): 31.07.2019 02:30 | vainqueur: Palmeiras | ||||
| H (Match allé) | LDU Quito | - | Club Olimpia | 3:1 (1:0) | ||
| R (match retour) | Club Olimpia | - | LDU Quito | 1:1 (1:1) | ||
| H (Match allé): 24.07.2019 02:30 | R (match retour): 31.07.2019 02:30 | vainqueur: LDU Quito | ||||
| H (Match allé) | Nacional | - | Internacional | 0:1 (0:0) | ||
| R (match retour) | Internacional | - | Nacional | 2:0 (1:0) | ||
| H (Match allé): 25.07.2019 00:15 | R (match retour): 01.08.2019 00:15 | vainqueur: Internacional | ||||
| H (Match allé) | San Lorenzo | - | Cerro Porteño | 0:0 (0:0) | ||
| R (match retour) | Cerro Porteño | - | San Lorenzo | 2:1 (0:1) | ||
| H (Match allé): 25.07.2019 00:15 | R (match retour): 01.08.2019 00:15 | vainqueur: Cerro Porteño | ||||
| H (Match allé) | Emelec | - | Flamengo RJ | 2:0 (1:0) | ||
| R (match retour) | Flamengo RJ | - | Emelec | 4:2 (2:0, 2:0) tab | ||
| H (Match allé): 25.07.2019 02:30 | R (match retour): 01.08.2019 02:30 | vainqueur: Flamengo RJ | ||||
| H (Match allé) | Athletico Paranaense | - | Boca Juniors | 0:1 (0:0) | ||
| R (match retour) | Boca Juniors | - | Athletico Paranaense | 2:0 (0:0) | ||
| H (Match allé): 25.07.2019 02:30 | R (match retour): 01.08.2019 02:30 | vainqueur: Boca Juniors | ||||
| H (Match allé) | Grêmio Porto Alegre | - | Libertad | 2:0 (0:0) | ||
| R (match retour) | Libertad | - | Grêmio Porto Alegre | 0:3 (0:3) | ||
| H (Match allé): 26.07.2019 02:30 | R (match retour): 02.08.2019 02:30 | vainqueur: Grêmio Porto Alegre | ||||
