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| H (Match allé) | Grêmio Porto Alegre | - | Palmeiras | 0:1 (0:1) | ||
| R (match retour) | Palmeiras | - | Grêmio Porto Alegre | 1:2 (1:2) | ||
| H (Match allé): 21.08.2019 02:30 | R (match retour): 28.08.2019 02:30 | vainqueur: Grêmio Porto Alegre | ||||
| H (Match allé) | LDU Quito | - | Boca Juniors | 0:3 (0:1) | ||
| R (match retour) | Boca Juniors | - | LDU Quito | 0:0 (0:0) | ||
| H (Match allé): 22.08.2019 00:15 | R (match retour): 29.08.2019 00:15 | vainqueur: Boca Juniors | ||||
| H (Match allé) | Flamengo RJ | - | Internacional | 2:0 (0:0) | ||
| R (match retour) | Internacional | - | Flamengo RJ | 1:1 (0:0) | ||
| H (Match allé): 22.08.2019 02:30 | R (match retour): 29.08.2019 02:30 | vainqueur: Flamengo RJ | ||||
| H (Match allé) | River Plate | - | Cerro Porteño | 2:0 (1:0) | ||
| R (match retour) | Cerro Porteño | - | River Plate | 1:1 (1:0) | ||
| H (Match allé): 23.08.2019 00:15 | R (match retour): 30.08.2019 00:15 | vainqueur: River Plate | ||||
