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| H (Match allé) | Flamengo RJ | - | River Plate | 1:2 (0:0) | ||
| R (match retour) | River Plate | - | Flamengo RJ | 4:3 (0:0) | ||
| H (Match allé): 31.10.2000 | R (match retour): 08.11.2000 | vainqueur: River Plate | ||||
| H (Match allé) | Vasco da Gama - RJ | - | Rosario Central | 1:0 (1:0) | ||
| R (match retour) | Rosario Central | - | Vasco da Gama - RJ | 4:5 (0:0, 1:0) tab | ||
| H (Match allé): 31.10.2000 | R (match retour): 08.11.2000 | vainqueur: Vasco da Gama - RJ | ||||
| H (Match allé) | Palmeiras | - | Cruzeiro | 3:2 (2:0) | ||
| R (match retour) | Cruzeiro | - | Palmeiras | 1:2 (0:1) | ||
| H (Match allé): 31.10.2000 | R (match retour): 08.11.2000 | vainqueur: Palmeiras | ||||
| H (Match allé) | Boca Juniors | - | Atlético Mineiro | 0:2 (0:1) | ||
| R (match retour) | Atlético Mineiro | - | Boca Juniors | 2:2 (1:2) | ||
| H (Match allé): 01.11.2000 | R (match retour): 07.11.2000 | vainqueur: Atlético Mineiro | ||||
