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| H (Match allé) | Estudiantes | - | River Plate | 1:2 (1:0) | ||
| R (match retour) | River Plate | - | Estudiantes | 3:2 (1:1) | ||
| H (Match allé): 30.10.2014 00:15 | R (match retour): 07.11.2014 01:30 | vainqueur: River Plate | ||||
| H (Match allé) | Atlético Nacional | - | Universidad Cesar Vallejo | 1:0 (0:0) | ||
| R (match retour) | Universidad Cesar Vallejo | - | Atlético Nacional | 0:1 (0:0) | ||
| H (Match allé): 30.10.2014 02:30 | R (match retour): 06.11.2014 03:30 | vainqueur: Atlético Nacional | ||||
| H (Match allé) | São Paulo FC | - | Emelec | 4:2 (3:0) | ||
| R (match retour) | Emelec | - | São Paulo FC | 3:2 (1:2) | ||
| H (Match allé): 30.10.2014 23:15 | R (match retour): 06.11.2014 01:00 | vainqueur: São Paulo FC | ||||
| H (Match allé) | Boca Juniors | - | Cerro Porteño | 1:0 (0:0) | ||
| R (match retour) | Cerro Porteño | - | Boca Juniors | 1:4 (1:1) | ||
| H (Match allé): 31.10.2014 01:30 | R (match retour): 06.11.2014 23:00 | vainqueur: Boca Juniors | ||||
