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| 30.09.2006 | 22:00 | Athletic Bilbao | - | FC Barcelona | 1:3 (1:1) | |
| 01.10.2006 | 18:00 | RCD Mallorca | - | Villarreal CF | 1:2 (0:2) | |
| 18:00 | Real Zaragoza | - | Levante UD | 2:2 (0:2) | ||
| 18:00 | Deportivo La Coruña | - | Real Sociedad | 2:0 (0:0) | ||
| 18:00 | Recreativo Huelva | - | Real Betis | 2:0 (0:0) | ||
| 18:00 | Real Madrid | - | Atlético Madrid | 1:1 (1:1) | ||
| 18:00 | Sevilla FC | - | Getafe CF | 1:0 (1:0) | ||
| 18:00 | Racing Santander | - | RC Celta | 1:1 (1:0) | ||
| 18:00 | Espanyol Barcelona | - | CA Osasuna | 0:0 (0:0) | ||
| 21:00 | Valencia CF | - | Gimnàstic de Tarragona | 4:0 (1:0) |
| # | Équipe | M. | G. | N. | P. | Buts | Diff. | Pts. | |
|---|---|---|---|---|---|---|---|---|---|
| 1 |
|
Valencia CF | 5 | 4 | 1 | 0 | 10:2 | 8 | 13 |
| 2 |
|
FC Barcelona | 5 | 4 | 1 | 0 | 13:4 | 9 | 13 |
| 3 |
|
Sevilla FC | 5 | 4 | 0 | 1 | 12:5 | 7 | 12 |
| 4 |
|
Real Madrid | 5 | 3 | 2 | 0 | 8:2 | 6 | 11 |
| 5 |
|
Atlético Madrid | 5 | 3 | 1 | 1 | 8:4 | 4 | 10 |
| 6 |
|
Deportivo La Coruña | 5 | 3 | 1 | 1 | 7:4 | 3 | 10 |
|
Recreativo Huelva | 5 | 3 | 1 | 1 | 7:4 | 3 | 10 | |
| 8 |
|
Real Zaragoza | 5 | 2 | 1 | 2 | 11:8 | 3 | 7 |
| 9 |
|
Getafe CF | 5 | 2 | 1 | 2 | 3:3 | 0 | 7 |
| 10 |
|
Villarreal CF | 5 | 2 | 1 | 2 | 5:6 | -1 | 7 |
| 11 |
|
CA Osasuna | 5 | 2 | 1 | 2 | 4:5 | -1 | 7 |
| 12 |
|
Levante UD | 5 | 2 | 1 | 2 | 6:10 | -4 | 7 |
| 13 |
|
RCD Mallorca | 5 | 1 | 2 | 2 | 3:5 | -2 | 5 |
| 14 |
|
RC Celta | 5 | 1 | 1 | 3 | 6:9 | -3 | 4 |
| 15 |
|
Gimnàstic de Tarragona | 5 | 1 | 1 | 3 | 4:10 | -6 | 4 |
| 16 |
|
Espanyol Barcelona | 5 | 1 | 1 | 3 | 2:6 | -4 | 4 |
| 17 |
|
Real Betis | 5 | 1 | 0 | 4 | 6:8 | -2 | 3 |
| 18 |
|
Racing Santander | 5 | 0 | 2 | 3 | 3:8 | -5 | 2 |
| 19 |
|
Athletic Bilbao | 5 | 0 | 2 | 3 | 3:11 | -8 | 2 |
| 20 |
|
Real Sociedad | 5 | 0 | 1 | 4 | 4:11 | -7 | 1 |
