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| 29.09.2012 | 16:00 | Valencia CF | - | Real Zaragoza | 2:0 (1:0) | |
| 18:00 | Málaga CF | - | Real Betis | 4:0 (2:0) | ||
| 20:00 | Real Sociedad | - | Athletic Bilbao | 2:0 (0:0) | ||
| 22:00 | Sevilla FC | - | FC Barcelona | 2:3 (1:0) | ||
| 30.09.2012 | 12:00 | Granada CF | - | RC Celta | 2:1 (2:1) | |
| 16:00 | Real Valladolid | - | Rayo Vallecano | 6:1 (4:1) | ||
| 18:00 | CA Osasuna | - | Levante UD | 4:0 (0:0) | ||
| 19:50 | Real Madrid | - | Deportivo La Coruña | 5:1 (3:1) | ||
| 21:30 | Espanyol Barcelona | - | Atlético Madrid | 0:1 (0:1) | ||
| 01.10.2012 | 21:30 | Getafe CF | - | RCD Mallorca | 1:0 (0:0) |
| # | Équipe | M. | G. | N. | P. | Buts | Diff. | Pts. | |
|---|---|---|---|---|---|---|---|---|---|
| 1 |
|
FC Barcelona | 6 | 6 | 0 | 0 | 17:5 | 12 | 18 |
| 2 |
|
Atlético Madrid | 6 | 5 | 1 | 0 | 16:7 | 9 | 16 |
| 3 |
|
Málaga CF | 6 | 4 | 2 | 0 | 10:2 | 8 | 14 |
| 4 |
|
Sevilla FC | 6 | 3 | 2 | 1 | 8:5 | 3 | 11 |
| 5 |
|
RCD Mallorca | 6 | 3 | 2 | 1 | 7:4 | 3 | 11 |
| 6 |
|
Real Madrid | 6 | 3 | 1 | 2 | 12:5 | 7 | 10 |
| 7 |
|
Real Valladolid | 6 | 3 | 0 | 3 | 10:6 | 4 | 9 |
| 8 |
|
Real Sociedad | 6 | 3 | 0 | 3 | 8:9 | -1 | 9 |
| 9 |
|
Real Betis | 6 | 3 | 0 | 3 | 10:13 | -3 | 9 |
| 10 |
|
Valencia CF | 6 | 2 | 2 | 2 | 8:8 | 0 | 8 |
| 11 |
|
Getafe CF | 6 | 2 | 1 | 3 | 7:10 | -3 | 7 |
| 12 |
|
Levante UD | 6 | 2 | 1 | 3 | 7:13 | -6 | 7 |
|
Rayo Vallecano | 6 | 2 | 1 | 3 | 7:13 | -6 | 7 | |
| 14 |
|
RC Celta | 6 | 2 | 0 | 4 | 7:8 | -1 | 6 |
| 15 |
|
Real Zaragoza | 6 | 2 | 0 | 4 | 5:8 | -3 | 6 |
| 16 |
|
Deportivo La Coruña | 6 | 1 | 3 | 2 | 8:12 | -4 | 6 |
| 17 |
|
Granada CF | 6 | 1 | 2 | 3 | 4:9 | -5 | 5 |
| 18 |
|
Athletic Bilbao | 6 | 1 | 2 | 3 | 8:14 | -6 | 5 |
| 19 |
|
CA Osasuna | 6 | 1 | 1 | 4 | 7:10 | -3 | 4 |
| 20 |
|
Espanyol Barcelona | 6 | 0 | 1 | 5 | 7:12 | -5 | 1 |
| Champions League | |
| Champions League Quali. | |
| Europa League | |
| Europa League Quali. | |
| Europa League Quali. | |
| Relégation |
