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| 20.10.2012 | 16:00 | Málaga CF | - | Real Valladolid | 2:1 (1:1) | |
| 18:00 | Real Madrid | - | RC Celta | 2:0 (1:0) | ||
| 20:00 | Valencia CF | - | Athletic Bilbao | 3:2 (1:2) | ||
| 22:00 | Deportivo La Coruña | - | FC Barcelona | 4:5 (2:4) | ||
| 21.10.2012 | 12:00 | Getafe CF | - | Levante UD | 0:1 (0:0) | |
| 16:00 | Espanyol Barcelona | - | Rayo Vallecano | 3:2 (1:1) | ||
| 17:50 | Granada CF | - | Real Zaragoza | 1:2 (0:2) | ||
| 19:45 | CA Osasuna | - | Real Betis | 0:0 (0:0) | ||
| 21:30 | Real Sociedad | - | Atlético Madrid | 0:1 (0:0) | ||
| 22.10.2012 | 21:30 | Sevilla FC | - | RCD Mallorca | 3:2 (1:2) |
| # | Équipe | M. | G. | N. | P. | Buts | Diff. | Pts. | |
|---|---|---|---|---|---|---|---|---|---|
| 1 |
|
FC Barcelona | 8 | 7 | 1 | 0 | 24:11 | 13 | 22 |
| 2 |
|
Atlético Madrid | 8 | 7 | 1 | 0 | 19:8 | 11 | 22 |
| 3 |
|
Málaga CF | 8 | 5 | 2 | 1 | 13:5 | 8 | 17 |
| 4 |
|
Real Madrid | 8 | 4 | 2 | 2 | 16:7 | 9 | 14 |
| 5 |
|
Sevilla FC | 8 | 4 | 2 | 2 | 11:9 | 2 | 14 |
| 6 |
|
Real Betis | 8 | 4 | 1 | 3 | 12:13 | -1 | 13 |
| 7 |
|
Levante UD | 8 | 4 | 1 | 3 | 9:13 | -4 | 13 |
| 8 |
|
RCD Mallorca | 8 | 3 | 2 | 3 | 10:9 | 1 | 11 |
| 9 |
|
Valencia CF | 8 | 3 | 2 | 3 | 11:11 | 0 | 11 |
| 10 |
|
Real Valladolid | 8 | 3 | 1 | 4 | 12:9 | 3 | 10 |
| 11 |
|
Getafe CF | 8 | 3 | 1 | 4 | 8:11 | -3 | 10 |
| 12 |
|
Rayo Vallecano | 8 | 3 | 1 | 4 | 11:17 | -6 | 10 |
| 13 |
|
RC Celta | 8 | 3 | 0 | 5 | 9:10 | -1 | 9 |
| 14 |
|
Real Zaragoza | 8 | 3 | 0 | 5 | 7:10 | -3 | 9 |
| 15 |
|
Real Sociedad | 8 | 3 | 0 | 5 | 8:12 | -4 | 9 |
| 16 |
|
Granada CF | 8 | 2 | 2 | 4 | 7:12 | -5 | 8 |
| 17 |
|
Athletic Bilbao | 8 | 2 | 2 | 4 | 11:17 | -6 | 8 |
| 18 |
|
Deportivo La Coruña | 8 | 1 | 3 | 4 | 13:19 | -6 | 6 |
| 19 |
|
Espanyol Barcelona | 8 | 1 | 2 | 5 | 11:15 | -4 | 5 |
| 20 |
|
CA Osasuna | 8 | 1 | 2 | 5 | 7:11 | -4 | 5 |
| Champions League | |
| Champions League Quali. | |
| Europa League | |
| Europa League Quali. | |
| Europa League Quali. | |
| Relégation |
