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| 27.10.2012 | 16:00 | Espanyol Barcelona | - | Málaga CF | 0:0 (0:0) | |
| 18:00 | Real Betis | - | Valencia CF | 1:0 (1:0) | ||
| 20:00 | RC Celta | - | Deportivo La Coruña | 1:1 (1:1) | ||
| 22:00 | Rayo Vallecano | - | FC Barcelona | 0:5 (0:1) | ||
| 28.10.2012 | 12:00 | Real Zaragoza | - | Sevilla FC | 2:1 (2:0) | |
| 16:00 | Levante UD | - | Granada CF | 3:1 (1:0) | ||
| 17:50 | Athletic Bilbao | - | Getafe CF | 1:2 (0:1) | ||
| 19:45 | Atlético Madrid | - | CA Osasuna | 3:1 (2:1) | ||
| 21:30 | RCD Mallorca | - | Real Madrid | 0:5 (0:2) | ||
| 29.10.2012 | 21:30 | Real Valladolid | - | Real Sociedad | 2:2 (1:1) |
| # | Équipe | M. | G. | N. | P. | Buts | Diff. | Pts. | |
|---|---|---|---|---|---|---|---|---|---|
| 1 |
|
FC Barcelona | 9 | 8 | 1 | 0 | 29:11 | 18 | 25 |
| 2 |
|
Atlético Madrid | 9 | 8 | 1 | 0 | 22:9 | 13 | 25 |
| 3 |
|
Málaga CF | 9 | 5 | 3 | 1 | 13:5 | 8 | 18 |
| 4 |
|
Real Madrid | 9 | 5 | 2 | 2 | 21:7 | 14 | 17 |
| 5 |
|
Real Betis | 9 | 5 | 1 | 3 | 13:13 | 0 | 16 |
| 6 |
|
Levante UD | 9 | 5 | 1 | 3 | 12:14 | -2 | 16 |
| 7 |
|
Sevilla FC | 9 | 4 | 2 | 3 | 12:11 | 1 | 14 |
| 8 |
|
Getafe CF | 9 | 4 | 1 | 4 | 10:12 | -2 | 13 |
| 9 |
|
Real Zaragoza | 9 | 4 | 0 | 5 | 9:11 | -2 | 12 |
| 10 |
|
Real Valladolid | 9 | 3 | 2 | 4 | 14:11 | 3 | 11 |
| 11 |
|
Valencia CF | 9 | 3 | 2 | 4 | 11:12 | -1 | 11 |
| 12 |
|
RCD Mallorca | 9 | 3 | 2 | 4 | 10:14 | -4 | 11 |
| 13 |
|
RC Celta | 9 | 3 | 1 | 5 | 10:11 | -1 | 10 |
| 14 |
|
Real Sociedad | 9 | 3 | 1 | 5 | 10:14 | -4 | 10 |
| 15 |
|
Rayo Vallecano | 9 | 3 | 1 | 5 | 11:22 | -11 | 10 |
| 16 |
|
Athletic Bilbao | 9 | 2 | 2 | 5 | 12:19 | -7 | 8 |
| 17 |
|
Granada CF | 9 | 2 | 2 | 5 | 8:15 | -7 | 8 |
| 18 |
|
Deportivo La Coruña | 9 | 1 | 4 | 4 | 14:20 | -6 | 7 |
| 19 |
|
Espanyol Barcelona | 9 | 1 | 3 | 5 | 11:15 | -4 | 6 |
| 20 |
|
CA Osasuna | 9 | 1 | 2 | 6 | 8:14 | -6 | 5 |
| Champions League | |
| Champions League Quali. | |
| Europa League | |
| Europa League Quali. | |
| Europa League Quali. | |
| Relégation |
