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| H (Match allé) | Libertad | - | Fortaleza | 0:1 (0:1) | ||
| R (match retour) | Fortaleza | - | Libertad | 1:1 (0:1) | ||
| H (Match allé): 02.08.2023 00:00 | R (match retour): 09.08.2023 00:00 | vainqueur: Fortaleza | ||||
| H (Match allé) | Emelec | - | Defensa y Justicia | 1:2 (1:0) | ||
| R (match retour) | Defensa y Justicia | - | Emelec | 1:0 (0:0) | ||
| H (Match allé): 02.08.2023 02:00 | R (match retour): 09.08.2023 02:00 | vainqueur: Defensa y Justicia | ||||
| H (Match allé) | Corinthians SP | - | Newell's Old Boys | 2:1 (0:1) | ||
| R (match retour) | Newell's Old Boys | - | Corinthians SP | 0:0 (0:0) | ||
| H (Match allé): 02.08.2023 02:30 | R (match retour): 09.08.2023 02:30 | vainqueur: Corinthians SP | ||||
| H (Match allé) | Botafogo - RJ | - | Guaraní | 2:1 (0:1) | ||
| R (match retour) | Guaraní | - | Botafogo - RJ | 0:0 (0:0) | ||
| H (Match allé): 03.08.2023 00:00 | R (match retour): 10.08.2023 00:00 | vainqueur: Botafogo - RJ | ||||
| H (Match allé) | Estudiantes | - | Goiás - GO | 3:0 (0:0) | ||
| R (match retour) | Goiás - GO | - | Estudiantes | 0:2 (0:1) | ||
| H (Match allé): 03.08.2023 00:00 | R (match retour): 10.08.2023 00:00 | vainqueur: Estudiantes | ||||
| H (Match allé) | San Lorenzo | - | São Paulo FC | 1:0 (0:0) | ||
| R (match retour) | São Paulo FC | - | San Lorenzo | 2:0 (1:0) | ||
| H (Match allé): 04.08.2023 00:00 | R (match retour): 11.08.2023 00:00 | vainqueur: São Paulo FC | ||||
| H (Match allé) | Ñublense | - | LDU Quito | 0:1 (0:0) | ||
| R (match retour) | LDU Quito | - | Ñublense | 4:3 (1:1, 2:3) tab | ||
| H (Match allé): 04.08.2023 02:00 | R (match retour): 11.08.2023 02:00 | vainqueur: LDU Quito | ||||
| H (Match allé) | América - MG | - | Red Bull Bragantino | 1:1 (0:1) | ||
| R (match retour) | Red Bull Bragantino | - | América - MG | 3:4 (2:2, 3:3) tab | ||
| H (Match allé): 04.08.2023 02:00 | R (match retour): 11.08.2023 02:00 | vainqueur: América - MG | ||||
