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| H (Match allé) | Corinthians SP | - | Estudiantes | 1:0 (1:0) | ||
| R (match retour) | Estudiantes | - | Corinthians SP | 2:3 (1:0, 1:0) tab | ||
| H (Match allé): 23.08.2023 02:30 | R (match retour): 30.08.2023 02:30 | vainqueur: Corinthians SP | ||||
| H (Match allé) | Botafogo - RJ | - | Defensa y Justicia | 1:1 (0:0) | ||
| R (match retour) | Defensa y Justicia | - | Botafogo - RJ | 2:1 (1:1) | ||
| H (Match allé): 24.08.2023 00:00 | R (match retour): 31.08.2023 00:00 | vainqueur: Defensa y Justicia | ||||
| H (Match allé) | América - MG | - | Fortaleza | 1:3 (0:3) | ||
| R (match retour) | Fortaleza | - | América - MG | 2:1 (1:0) | ||
| H (Match allé): 25.08.2023 00:00 | R (match retour): 01.09.2023 00:00 | vainqueur: Fortaleza | ||||
| H (Match allé) | LDU Quito | - | São Paulo FC | 2:1 (2:0) | ||
| R (match retour) | São Paulo FC | - | LDU Quito | 4:5 (0:0, 1:0) tab | ||
| H (Match allé): 25.08.2023 00:00 | R (match retour): 01.09.2023 00:00 | vainqueur: LDU Quito | ||||
