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| H (Match allé) | Udinese Calcio | - | ACF Fiorentina | 2:1 (1:1) | ||
| R (match retour) | ACF Fiorentina | - | Udinese Calcio | 2:0 (1:0) | ||
| H (Match allé): 04.02.2014 21:00 | R (match retour): 11.02.2014 21:00 | vainqueur: ACF Fiorentina | ||||
| H (Match allé) | AS Roma | - | SSC Napoli | 3:2 (2:0) | ||
| R (match retour) | SSC Napoli | - | AS Roma | 3:0 (1:0) | ||
| H (Match allé): 05.02.2014 20:45 | R (match retour): 12.02.2014 20:45 | vainqueur: SSC Napoli | ||||
